Gore-Tex vs. some generic undisclosed material. USA vs. Asia. No contest.
Sure, after (?) years Patagonia will send you a new pair. They paid under $50. in the first place. Simms on the other hand... Last time I checked, you could replace the booties, including size, on Simms for $50.
Disclosure: I am a diehard Simms customer. Just so you know.